Photochemical studies processes electric-field coalescence silver atoms in microcrystals halides

Authors

  • Shishkanov O.N. Kuban State University, Krasnodar, Российская Федерация
  • Boychenko A.P. Kuban State University, Krasnodar, Российская Федерация
  • Yakovenko N.A. Kuban State University, Krasnodar, Российская Федерация

UDC

535.37

Abstract

By known methods and techniques of chemical-photographic processing silver halide photographic materials presented research electric-coalescence of atoms in microscopic silver halide him an example of X-ray photographs. It is shown that the developing agent as effective reducing agents in various combinations with each other and the other components of the developing solution to provide differential action centers of latent electric-field image depending on the morphology of the microcrystals AgHal, shaped voltage pulses of different polarities. The features of this action on the plate microcrystals AgHal hetero-contact type of X-ray film "Agfa", consisting in the absence of manifest differences electro-field images for bipolar pulses. Using known techniques locking surface mobility of the ions Ag+, separation images in the depth and surface components shown that Ag-centers electric-field of latent images are formed mainly on the surface only in terms of homogeneous microcrystals. In the case of T-crystal structure of the nuclear-film "Agfa" almost half of these centers are concentrated in their depths. Moreover, in the negative polarity voltage pulses share depth imaging is 45% more of the same image formed on the pulse of positive polarity. For the studied films "Agfa" and "PT-4sh" defined thresholds the electric field strength at which begins the formation of a reliable electric-image, that is effective clustering of silver atoms. Based on the results of the research laid the foundations of metrology electric-field for photos with specific parameters AgHal-films - electric-field sensitivity and electric-field exposure.

Keywords:

electric-field coalescence, electro-field image, silver halides, clusters of silver, electric-field sensitivity, electric-field exposure

Author Infos

Oleg N. Shishkanov

аспирант кафедры оптоэлектроники Кубанского государственного университета

e-mail: shishkanovoleg@mail.ru

Aleksandr P. Boychenko

д-р физ.-мат. наук, доц. кафедры оптоэлектроники Кубанского государственного университета

e-mail: bojchenco@yandex.ru

Nikolay A. Yakovenko

д-р техн. наук, проф., зав. кафедрой оптоэлектроники Кубанского государственного университета

e-mail: dean@phys.kubsu.ru

References

  1. Latyshev A.N., Ovchinnikov O.V., Smirnov M.S. i dr. Spektral'no-kontroliruemaja poatomnaja fotosborka klasterov serebra na poverhnosti ionno-kovalentnyh kristallov [Spectral-controlled atom-wise assembly of silver clusters on the surface of the ion-covalent crystals]. Optika i spektroskopija [Optics and Spectroscopy], 2010, vol. 109, pp. 719-728. (In Russian)
  2. Brune H. Surface diffusion: shifting strings. Nature, 2003, Vol. 2, pp. 778-779.
  3. Kravcov A.E., Kizema I.G., Karpljuk A.I. i dr. Jelektrograficheskij kontrol' mikrodefektnosti dijelektricheskih sloev [Electrographic control microdefects dielectric layers]. Jelektronnaja tehnika [Electronic Engineering], 1973, iss. 6(16), pp. 150-153. (In Russian)
  4. Reznikov M.A. Fizicheskaja priroda jelektrotopograficheskogo jeffekta v fotograficheskih jemul'sijah. Avtoref. dis. kand. fiz-mat. nauk [The physical nature of electrotopographic effect in the photographic emulsions. PhD. phys. and math. sci. diss. abstract]. Kiev, 1981. 22 p. (In Russian)
  5. Kravcov A.E., Pipa V.A., Reznikov M.A., Fok M.V. Jelektrotopo-graficheskij jeffekt v fotojemul'sijah i ego primenenie [Electrotopografic effect in photo emulsions and its application]. Trudy FIAN im. P.N. Lebedeva [Proc. of the FIAN named P.N. Lebedev], 1981, vol. 129, pp. 13-65. (In Russian)
  6. Avgustinovich K.A. Osnovy fotograficheskoj metrologii [Basics photographic metrology]. Moscow, Leg-prombytizdat Publ., 1990, 288 p.
  7. Reznikov M.A. Jelektrofizicheskie svojstva fotograficheskogo jemul'sionnogo sloja [Electrical Properties of photographic emulsion layer]. Zhurnal nauchnoj i prikladnoj fotografii i kinematografii [Journal of Scientific and Applied Photography and Cinematography], 1984, vol. 29, no 1, pp. 46-51. (In Russian)
  8. Biesen J.V. Maxwell-Wagner effect in silve bromide emulsion. J. Appl. Phys., 1970, vol. 41, no. 5. pp. 1910-1914.
  9. Takada S. Ionic conduction and space layer in silver halide photographic emulsion grains. Phot. Sci. Engineering, 1974, vol. 18, no. 5. pp. 500-503.
  10. Bogachev N.E., Shishkanov O.N., Tret'jakov A.M., Bojchenko A.P. Istochnik vysokovol'tnogo naprjazhenija dlja jelektrotopografii [High voltage device for electrotopography]. Dostizhenija vuzovskoj nauki: Sb. nauch. tr. [Achievements of university research: Coll. of sci. works]. Novosibirsk, NGTU Publ., 2012. pp. 116-120. (In Russian)
  11. Zaks M.I., Poljanskaja Je.N. Tehnologija obrabotki fotokinomaterialov [The technology of processing photos and film materials]. Moscow, Legkaja i pishhevaja promyshlennost' Publ., 1983. 168 p. (In Russian)
  12. Zhurba Ju.I. Kratkij spravochnik po fotograficheskim processam i materialam [A short guide to photographic processes and materials]. Moscow, Iskusstvo Publ., 1991. 352 p. (In Russian)
  13. Mikulin V.P. Fotograficheskij recepturnyj spravochnik [Photographic prescription Directory]. Moscow, Iskusstvo Publ., 1969. 320 p. (In Russian)
  14. Pevchev Ju.F., Konovalova L.P. O vlijanii impul'snogo jelektricheskogo polja na topografiju skrytogo fotograficheskogo izobrazhenija [The effect of pulsed electric-field on the topography of the latent image]. Zhurnal nauchnoj i prikladnoj fotografii i kinematografii [Journal of Scientific and Applied Photography and Cinematography], 1970, vol. 15, no. 2, pp. 145-147. (In Russian)
  15. Breslav Ju.A., Pejsahov V.V., Kaplun L.Ja. Sintez i svojstva T-kristallov [Synthesis and properties of T-crystals]. Moscow, NIITJeHIM Publ., 1986, 60 p. (In Russian)
  16. Shishkanov O.N., Bojchenko A.P. O vysokoj jelektropolevoj chuvst-vitel'nosti rentgenovskoj fotoplenki "Agfa" [The high sensitivity of the electric-field X-ray film "Agfa"]. Voprosy obrazovanija i nauki: teoreticheskie i metodicheskie aspekty: Sb. nauch. tr. [Education and Science: theoretical and methodological aspects]. Tambov, OOO "Konsaltingovaja kompanija Jukom" Publ., 2014, iss. 8, pp. 170-171. (In Russian)
  17. Shishkanov O.N., Bojchenko A.P. O vysokoj chuvstvitel'nosti rentgenovskoj fotoplenki "Agfa" k nizkochastotnomu jelektricheskomu polju [The high sensitivity of the X-ray film "Agfa" to low frequency electric field]. Novoe slovo v nauke i praktike: gipotezy i aprobacija rezul'tatov issledovanij: Sb. nauch. tr. [The new word in the science and practice: the hypothesis testing and the results of research]. Ed S.S. Chernov. Novosibirsk: CRNS Publ., 2014. pp. 124-128. (In Russian)
  18. Shishkanov O.N. Registracija jelektrotopograficheskogo jeffekta na galogenserebrjanyh materialah dlja rentgenografii [Register of electrotopografic effect on silver halide X-ray materials]. Pokolenie budushhego: vzgljad molodyh uchenyh - 2012: Sb. nauch. tr. [Generation of the Future: A View of young scientists - 2012]. Kursk: JuZGU Publ., 2012, vol. 2, pp. 253-256. (In Russian)

Issue

Pages

89-100

Submitted

2015-05-17

Published

2015-06-25

How to Cite

Shishkanov O.N., Boychenko A.P., Yakovenko N.A. Photochemical studies processes electric-field coalescence silver atoms in microcrystals halides. Ecological Bulletin of Research Centers of the Black Sea Economic Cooperation, 2015, no. 2, pp. 89-100. (In Russian)