Mathematical and numerical process modeling of regulation pH of dilute solutions of electrolytes by electrodialysis with bipolar membranes in long channels

Authors

  • Vasilenko P.A. Kuban State University, Krasnodar, Российская Федерация
  • Lebedev K.A. Kuban State University, Krasnodar, Российская Федерация

UDC

517.958:544.6

DOI:

https://doi.org/10.31429/vestnik-15-1-41-49

Abstract

A hierarchical system of point models of water softening has been developed. The hierarchy of models has a linear ordering, each next one is built on the basis of the previous one, by including new equations reflecting the appearance of new substances, ions, and consequently new phenomena. The number of roots of the system of equations increases. Numerical methods for finding the roots of non-linear equations with the use of modified Newton methods with a choice of a step, a regularization parameter, and an extension method for systems of nonlinear equations are proposed.

Keywords:

electrodialysis, bipolar membrane, numerical modeling, correction of pH diluted solution, modified Newton method, mathematical model

Acknowledgement

Работа выполнена при финансовой поддержке гранта РФФИ и администрации Краснодарского края №16-48-230433р_а.

Author Infos

Polina A. Vasilenko

аспирантка кафедры вычислительной математики и информатики Кубанского государственного университета

e-mail: polig@mail.ru

Konstantin A. Lebedev

д-р физ.-мат. наук, профессор кафедры вычислительной математики и информатики Кубанского государственного университета

e-mail: klebedev.ya@yandex.ru

References

  1. Vasilenko P.A., Utin S.V., Zabolockij V.I., Lebedev K.A. Mathematical model of the correction of pH softened water in a long channel of electrodialysis with bipolar membrane. Nauchnyj zhurnal KubGAU [Scientific Journal of KubSAU]. 2017, no 126(02). Available at: http://ej.kubagro.ru/archive.asp?n=126 (accessed date 23.10.2017). (In Russian)
  2. Zabolockij V.I., Utin S.V., Lebedev K.A., Vasilenko P.A., Shel'deshov N.V. Study of pH correction process of chloride-bicarbonate dilute solutions by electrodialysis with bipolar membranes. Russ. J. Electrochem., 2012, vol. 48, no 7, pp. 842-847. (In Russian)
  3. Zabolotskii V.I., Utin S.V., Shel'deshov N.V., Lebedev K.A., Vasilenko P.A. Correction of pH of diluted solutions of electrolytes by electrodialysis with bipolar membranes. Russ. J. Electrochem., 2011, vol. 47, P. 321–326. doi: 10.1134/S1023193511030141
  4. Zabolotsky V., Vasilenko P., Utin S., Lebedev K. Theoretical and experimental investigation of the PH correction process of softened water in long electrodialysis channels with bipolar membranes. In: Proc. of Int. conf. "Ion transport in organic and inorganic membranes", Krasnodar-Sochi, Russia, May 23-27, pp. 417-418.
  5. Senik Yu.V. Theoretical and experimental study of electro-membrane treatment processes of natural water. Diss. … cand. phys.-math. science]. Krasnodar, 2005. (In Russian)
  6. Zabolockij V.I., Nikonenko V.V. Transfer of ions in membranes. Nauka, Moscow, 1996. (In Russian)
  7. Lebedev K.A. Ecologically clean electrodialysis technologies. Mathematical modeling of ion transport in multilayer membrane systems Diss. … dr. phys.-math. science. Krasnodar, 2002. (In Russian)
  8. Zabolockij V.I., Lebedev K.A., Urtenov M.H., Nikonenko V.V., Vasilenko P.A., SHaposhnik V.A. Mathematical model for describing current-voltage curves and transport numbers under intensive electrodialysis regimes. Russ. J. Electrochem. 2013. vol. 49, no.4. pp. 416-427. (In Russian)
  9. Lebedev K.A. On one method of finding the initial approximation for the Newton method. Zhurnal vychislitel'noy matematiki i matematicheskoy fiziki [J. of Computational Math. and Mathematical Phys.], 1996, vol. 36, no 3, pp. 6-14. (In Russian)
  10. Demidovich B.P., Maron I.A. Foundations of Computational Mathematics. Nauka, Moscow, 1966. (In Russian)
  11. Zhanlav T., Puzynin I.V. The convergence of iterations based on a continuous analogue of Newton's method. Zhurn. vychisl. matem. i matem. fiziki [J. of Computational Mathematics and Mathematical Physics], 1992, vol. 32, no. 6, pp. 846-856. (In Russian)
  12. Ortega Dzh., Rejnboldt V. Iterative methods for solving nonlinear systems of equations with many unknowns. Mir, Moscow, 1975. (In Russian)
  13. Pchelincev M.V., Skorkin N.A. The geometric meaning of Newton's method. Vestnik UrGU [Bulletin of the South Ural State University], 2009, no. 22, pp. 4-12. (In Russian)

Issue

Section

Physics

Pages

41-49

Submitted

2017-10-23

Published

2018-03-19

How to Cite

Vasilenko P.A., Lebedev K.A. Mathematical and numerical process modeling of regulation pH of dilute solutions of electrolytes by electrodialysis with bipolar membranes in long channels. Ecological Bulletin of Research Centers of the Black Sea Economic Cooperation, 2018, vol. 15, no. 1, pp. 41-49. DOI: https://doi.org/10.31429/vestnik-15-1-41-49 (In Russian)