Spectral and conductive characteristics of fullerene-based thin-film structures
UDC
53.06, 538.9, 621.31, 621.38DOI:
https://doi.org/10.31429/vestnik-16-2-48-58Abstract
In the present paper we consider carbon films obtained by the method of sequential deposition from fullerene solutions in various types of solvents. Micrographs are presented to estimate the surface geometry of thin-film structures. So, using various solvents, it is possible to form various geometrical objects depending on the functional purpose of the films. At the same time, nanostructured objects can have the form of both bulk polygons (in our case, hexagons) and star-shaped branching structures. The IR spectra of the obtained samples were analyzed and their comparative characteristics were given for a volume of a precipitated solution of 0.15 ml and 1 ml. Depending on the type of initial solvent, both solvent peaks, fullerene, and complex organic impurities can be present in the fabricated samples. From the presence of solvent peaks, it is possible to make an assumption about the crystallization of solvates and their preservation in the film after drying. The conductive properties of thin-film structures are investigated. The use of five types of solvents made it possible to change linear resistances from hundreds to thousands of GOhms with a volume of 0.15 ml applied. An increase in the volume of the nanocrystalline fraction (1 ml of solution) made it possible to reduce the resistance to tens of GOhms
It is worth noting that the mechanisms of the action of the active solvent environment on the morphology of the synthesized objects are not entirely clear, however, studies conducted to obtain nanostructures from fullerene solutions will be effective and, in our opinion, for controlled self-assembly of other functional organic systems.
Keywords:
fullerene, C60, solvent, current-voltage characteristic, thin-film structures, topologyReferences
- Sidorov, L.N., Yurovskaya, M.A., Borshchevskiy, A.Ya., Trushkov, I.V., Ioffe, I.N. Fullerenes. Ekzamen, Moscow, 2005. P. 688. (In Russian)
- Zhang, Y., Murtaza, I., Meng, H. Development of fullerenes and their derivatives as semiconductors in field-effect transistors: exploring the molecular design. J. Mater. Chem. C, 2018, vol. 6, iss. 14. P. 3514–3537.
- Agap'yev, K.B., Vrubel', I.I., Polozkov, R.G., Ivanov, V.K. Vychisleniya potentsiala i raspredeleniya elektronnoy plotnosti fullerenov C60+, C60 i C60- [Calculations of the potential and distribution of the electron density of fullerenes C60+, C60 and C60-] Nedelya nauki SPbPU [J. Science Week SPbPU], 2016, pp. 314–316. (In Russian)
- Moet D.J.D., Bruyn P., Kotlarski J.D., Blom. P.W.M. Enhanced efficiency in double junction polymer:fullerene solar cells. Organic Electronics, 2010, vol. 11, pp. 1821–1827.
- Gattia, T., Menna, E., Meneghetti, M., Maggini, M., Petrozza, A., Lamberti, F. The Renaissance of fullerenes with perovskite solar cells. Nano Energy, 2017, vol. 41, pp. 8–100.
- Belousova, I.M., Danilov, O.B., Sidorov, A.I. Nelineyno-opticheskiye ogranichiteli lazernogo izlucheniya. [Nonlinear optical limiters of laser radiation]. Opticheskiy zhurnal [Optical magazine], 2009, vol. 76, no. 4, pp. 71–85.
- Park, S., Srivastava, D., Cho, K. Generalized chemical reactivity of curved surfaces: carbon nanotubes. Nanotechnology, 2001, vol. 12, iss. 3, pp. 245–249.
- Vasconcelos, R.C., Aleixo, V.F.P., Del Nero, J. Organic field effect transistor composed by fullerene C60 and heterojunctions. Physica E: Low-dimensional Systems and Nanostructures, 2017, vol. 86, pp. 142–145.
- Li, Z., Zhang, Q., Zhang, C., Li, H., Lu, J. High quality fullerene film based on electrophoresis deposition for RRAM device application. Organic Electronics, 2019, vol. 66. P. 70–75.
- Dao, T.T., Matsushima, T., Murata, H. Organic nonvolatile memory transistors based on fullerene and an electron-trapping polymer. Organic Electronics, 2012, vol. 13, pp. 2709–2715.
- Mazinov, A.S., Rabotyagov, K.V., Gurchenko, V.S., Tyutyunik, A.S. Vliyanie strukturnyh osobennostej fullerensoderzhashchego materiala na yego rezistivnye svojstva [Influence of structural features of fullerene-containing material on its resistive properties]. Ekologicheskiy vestnik nauchnykh tsentrov Chernomorskogo ekonomicheskogo sotrudnichestva [Ecological Bulletin of Research Centers of the Black Sea Economic Cooperation], 2018, vol. 15, no. 2, pp. 86–93. (In Russian)
- Shevchenko, A.I., Rabotyagov, K.V., Maksimova, E.M., Naukhatskiy, I.A., Batiashvili, L.A. Fullerensoderzhashchij material, poluchennyj nizkotemperaturnym krekingom iz rezinosoderzhashchih othodov [Fullerene-containing material received by low-temperature cracking from rubber-containing wastes]. Vestnik Tambovskogo universiteta. Seriya Estestvennye i tekhnicheskie nauki [Tambov University Reports. Series: Natural and Technical Sciences], 2017, vol. 22, iss. 2, pp. 459–463. DOI: 10.20310/1810-0198-2017-22-2-459-463 (In Russian)
- Rabotyagov, K.V., Say, E.V., Maksimova, E.M., Nauhacky, I.A., Karpenko, N.I., Shevchenko, A.I., Mazinov, A.S. Issledovanie struktury i fiziko-himicheskih svojstv poristyh uglerodnyh materialov, poluchennyh nizkotemperaturnym krekingom [Investigation of the structure and physicochemical properties for porous carbon materials obtained by low- temperature cracking]. Uchyonye zapiski Krymskogo federal'nogo universiteta imeni V.I. Vernadskogo. Biologiya. Himiya [Scientific Notes of V.I. Vernadsky Crimean Federal University. Biology. Chemistry], 2015, vol. 1 (67), iss. 3, pp. 125–131. (In Russian)
- Bezmel'nitsyn, V.N., Yeletskiy, A.V., Okun', M.V. Fullereny v rastvorakh [Fullerenes in solutions]. Uspekhi fizicheskikh nauk [Advances in the physical sciences], 1998, vol. 168, iss. 11, pp. 1196–1219. (In Russian)
- Mazinov, A.S., Gurchenko, V.S., Tyutyunik, A.S., Shevchenko, A.I. Vliyaniye strukturnykh osobennostey fullerensoderzhashchego materiala na yego rezistivnyye svoystva pri osazhdenii iz rastvora [The influence of the structural features of the fullerene-containing material on its resistive properties during deposition from solution]. Ekologicheskiy vestnik nauchnykh tsentrov Chernomorskogo ekonomicheskogo sotrudnichestva [Ecological Bulletin of Research Centers of the Black Sea Economic Cooperation], 2018, vol. 15, no. 4, pp. 85–92. (In Russian)
Downloads
Submitted
Published
How to Cite
Copyright (c) 2019 Mazinov A.A., Gurchenko V.S., Shevchenko A.I., Arutinov N.E., Tutunik A.S.
This work is licensed under a Creative Commons Attribution 4.0 International License.
