Catalytic soot combustion in presence of molybdates Li2Cu2-xAgx(MoO4)3

Authors

  • Karpovich N.F. Institute of Materials Science, Khabarovsk Scientific Center, Far-Eastern Branch of the Russian Academy of Sciences, Khabarovsk, Russian Federation
  • Lebukhova N.V. Institute of Materials Science, Khabarovsk Scientific Center, Far-Eastern Branch of the Russian Academy of Sciences, Khabarovsk, Russian Federation
  • Makarevich K.S. Institute of Materials Science, Khabarovsk Scientific Center, Far-Eastern Branch of the Russian Academy of Sciences, Khabarovsk, Russian Federation
  • Chigrin P.G. Institute of Materials Science, Khabarovsk Scientific Center, Far-Eastern Branch of the Russian Academy of Sciences, Khabarovsk, Russian Federation
  • Kirichenko E.A. Institute of Materials Science, Khabarovsk Scientific Center, Far-Eastern Branch of the Russian Academy of Sciences, Khabarovsk, Russian Federation

UDC

541.128.3+66.048.6

Abstract

The synthesis of Li2Cu2-xAgx(MoO4)3 phases ($0\le x\le 0.1$), which have monoclinic syngony and structural type of Li2Cu2(MoO4)3, was carried out. It was shown that molybdates Li2Cu2(MoO4)3 and Ag2Cu2(MoO4)3 possess by catalytic ability in soot oxidation process and can substantially reduce CO yield in combustion products. The Ag additive to Li2Cu2(MoO4)_3$ molybdate in range $0\le x\le 0.1$ leads to soot ignition temperature reduction from 408° to 382°C (587°C at uncatalytic combustion). The obtained results are useful at development of diesel exhaust emission abatement catalysts.

Keywords:

catalytic soot combustion, double molybdates, CO conversion

Author info

  • Natalya F. Karpovich

    канд. хим. наук, старший научный сотрудник Института материаловедения Хабаровского научного центра Дальневосточного отделения РАН

  • Natalya V. Lebukhova

    канд. хим. наук, ведущий научный сотрудник Института материаловедения Хабаровского научного центра Дальневосточного отделения РАН

  • Konstantin S. Makarevich

    канд. техн. наук, научный сотрудник Института материаловедения Хабаровского научного центра Дальневосточного отделения РАН

  • Pavel G. Chigrin

    аспирант Института материаловедения Хабаровского научного центра Дальневосточного отделения РАН

  • Evgeniy A. Kirichenko

    аспирант Института материаловедения Хабаровского научного центра Дальневосточного отделения РАН

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Issue

No. 2 (2010)

Pages

42-45

Section

Article

Dates

Submitted

June 7, 2010

Accepted

June 8, 2010

Published

June 30, 2010

How to Cite

[1]
Karpovich, N.F., Lebukhova, N.V., Makarevich, K.S., Chigrin, P.G., Kirichenko, E.A., Catalytic soot combustion in presence of molybdates Li2Cu2-xAgx(MoO4)3. Ecological Bulletin of Research Centers of the Black Sea Economic Cooperation, 2010, № 2, pp. 42–45.

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Copyright (c) 2010 Карпович Н.Ф., Лебухова Н.В., Макаревич К.С., Чигрин П.Г., Кириченко Е.А.

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This work is licensed under a Creative Commons Attribution 4.0 International License.