Optical properties of multicomponent borate glasses doped with trivalent terbium ions

Authors

UDC

538.958:535.37

DOI:

https://doi.org/10.31429/vestnik-21-2-93-102

Abstract

The paper presents the results of studies of spectral and luminescent properties of new series glass multi compositions based on borate and bismuth glass heavily doped with terbium, and investigate the regularity of the characteristics of the obtained samples at different concentrations of bismuth and activator and the mutual effect on the borate glass matrix. It is shown that the intensity of spontaneous radiation increases with an increase in the concentration of terbium. Three main absorption bands were found due to fluctuations of complexes in borate glass. Characteristic absorption peaks of terbium ions at 367, 377 and 485 nm are observed, corresponding to the transitions 7F65D4, 7F65G6, 7F65L10. The physical parameters of a multicomponent glass doped with Tb3+ ions are calculated. The resulting phosphors have high photoluminescent properties and can be used in various optical applications.

Keywords:

borate glasses, forbidden zone, luminescence, lifetime

Acknowledgement

The study did not have sponsorship.

Author Infos

Alaa Hammoud

канд. физ.-мат. наук, доцент кафедры радиофизики и нанотехнологий Кубанского государственного университета

e-mail: allahammsss@gmail.com

Vladislav A. Isaev

д-р физ.-мат. наук, профессор, профессор кафедры теоретической физики и компьютерных технологий Кубанского государственного университета

e-mail: vlisaev.v@yandex.ru

References

  1. Alzahrani, J.S., Alrowaili, Z.A., Eke, C., Al-Qaisi, S., Alsufyani, S.J., Olarinoye, I.O., Boukhris, I., Al-Buriahi, M.S., Tb3+-doped GeO2-B2O3–P2O5–ZnO magneto-optical glasses: Potential application as gamma-radiation absorbers. Radiation Physics and Chemistry, 2023, vol. 208(11), art. 110874. DOI: 10.1016/j.radphyschem.2023.110874
  2. Kesavulu, C.R., Kim, H.J., Lee, S.W., Kaewkhao, J., Kaewnuam, E., Wantana, N., Luminescence properties and energy transfer from Gd3+ to Tb3+ ions in gadolinium calcium silicoborate glasses for green laser application. J. Alloys Compd., 2017, vol. 704, pp. 557–564. DOI: 10.1016/j.jallcom.2017.02.056
  3. Swapna, K., Mahamuda, Sk., Srinivasa Rao, A., Jayasimhadri, M., Shakya, Suman, Prakash, G. Vijaya, Tb3+ doped Zinc Alumino Bismuth Borate glasses for green emitting luminescent devices. Journal of Luminescence, 2014, vol. 156, pp. 180–187. DOI: 10.1016/j.jlumin.2014.08.019
  4. Abbas, B.K., Baki, S.O., Leng, F.W., Abbas, H.K., Al-Sarraj, L., Mahdi, M.A., Investigation of Structural, Thermal Properties and Shielding Parameters of Borosilicate Glasses Doped with Dy3+/Tb3+ Ions for Gamma and Neutron Radiation Shielding Applications. Journal of Advanced Research in Fluid Mechanics and Thermal Sciences, 2021, vol. 80(1), pp. 50–61. DOI: 10.37934/arfmts.80.1.5061
  5. Linganna, K., Sreedhar, V.B., Jayasankar, C.K., Luminescence properties of Tb3+ ions in zinc fluorophosphates glasses for green laser applications. Mater. Res. Bull., 2015, vol. 67, pp. 196–200. DOI: 10.1016/j.materresbull.2015.02.062
  6. Alrowaili, Z.A., Basha, B., Alwadai, N., Olarinoye, I.O., Hammoud, A., Al-Buriahi, M.S., V. Stroganova, E.V., Sriwunkum, C., Experimental design and characterization of Eu-doped tellurite matrix glassy composite for medical and ionizing-radiation sensing applications. Ceramics International, 2023, vol. 49, iss. 12, pp. 20772–20783. DOI: 10.1016/j.ceramint.2023.03.209.
  7. Altowyan, A.S., Hammoud, A., Al-Qaisi, S., Alwadai, N., Lebedev, A.V., Klimenko, V.A., Vasileva, L.V., Al-Buriahi, M.S., Synthesis, XRD, UV-Vis spectra and photoluminescent properties of TeO2-based glasses doped with Yb3+ and Bi3+. Optik, 2022, vol. 268, art. 169808. DOI: 10.1016/j.ijleo.2022.169808
  8. Farouk, M., Samir, A., Metawe, F., Elokr, M., Optical absorption and structural studies of bismuth borate glasses containing Er3+ ions. Journal of Non-Crystalline Solids, 2013, vol. 371–372, pp. 14–21. DOI: 10.1016/j.jnoncrysol.2013.04.001
  9. Kumar, A., Kaur, R., Sayyed, M.I., Rashad, M., Singh, M., Ali, A.M., Physical, structural, optical and gamma ray shielding behavior of (20+x)PbO-10BaO-10Na2O-10MgO-(50-x)B2O3 glasses. Phys. B Condens. Matter, 2019, vol. 552, pp. 110–118. DOI: 10.1016/j.physb.2018.10.001
  10. Vishal, K., Pandey, O.P., Singh, K., Structural and optical properties of barium borosilicate glasses. Phys. B Condens. Matter, 2010, vol. 405, pp. 204–207. DOI: 10.1016/j.physb.2009.08.055
  11. Laariedh, F., Sayyed, M.I., Kumar, A., Tekin, H.O., Kaur, R., Badech, T.-B., Studies on the structural, optical and radiation shielding properties of (5,0 – x) PbO – 10WO3–10Na2O – 10MgO – (20 + x)B2O3 glasses. J. Non-Cryst. Solids, 2019, vol. 513, pp. 159–166. DOI: 10.1016/j.jnoncrysol.2019.03.007
  12. Kaur, R., Singh, S., Singh, K., Pandey, O.P., Effect of swift heavy ions on structural and optical properties of bismuth based alumina borosilicate glasses. Radiat. Phys. Chem., 2013, vol. 86, pp. 23–30. DOI: 10.1016/j.radphyschem.2013.01.031
  13. Priyanka Goyal, P., Sharma,Y.K., Pal, S., Bind, U.C., Huang, S.C., Chung, S.L. The effect of SiO2 content on structural, physical and spectroscopic properties of Er3+ doped B2O3. J. Non-Cryst. Solids, 2017, vol. 463, pp. 118–127. DOI: 10.1016/j.jnoncrysol.2017.03.009
  14. Alzahrani, J.S., Hammoud, A., Altowyan, A.S., Olarinoyec, I.O. Lebedev, A.V., Al-Buriahi, M.S., Influence of Sm/Bi substitution on synthesis, structural, and photon interaction properties of TeO single bond MoO3 single bond BaO single bond Sm2O3 single bond Bi2O3 glass system. Optik, 2023, vol. 274, art. 170507. DOI: 10.1016/j.ijleo.2023.170507
  15. Tauc, J., Menth, A., Wood, D.L., Optical and Magnetic Investigations of the Localized States in Semiconducting Glasses. Phys. Rev. Letters, 1970, vol. 25, pp. 749–752. DOI: 10.1103/PhysRevLett.25.749
  16. Li, X., Zhu, H., Wei, J., Wang, K., Xu, E., Li, Z., Wu, D., Determination of band gaps of self-assembled carbon nanotube films using Tauc/Davis–Mott model. Appl. Phys. A, 2009, vol. 97, pp. 341–344. DOI: 10.1007/s00339-009-5330-z
  17. Dimitrov, V., Sake, S., Electronic oxide polarizability and optical basicity of simple oxides. I. Journal of Applied Physics, 1996, vol. 79, pp. 1736–1740. DOI: 10.1063/1.360962
  18. Mohan, S., Thind, K., Optical and spectroscopic properties of neodymium doped cadmium-sodium borate glasses. Optics and Laser Technology, 2017, vol. 95, pp. 36–41. DOI: 10.1016/j.optlastec.2017.04.016
  19. Sayyeda, M.I., Aşkın, A., Ali, A.M., Kumard, A., Rashada, M. Alshehric, A.M., Extensive study of newly developed highly dense transparent PbO-WO3-BaO-Na2O-B2O3 glasses for radiation shielding applications. Journal of Non-Crystalline Solids, 2019, vol. 521, art. 119521. DOI: 10.1016/j.jnoncrysol.2019.119521
  20. Tamam, N., Alrowaili, Z.A., Hammoud, A., Lebedev, A.V., Boukhris, I., Olarinoye, I.O., Al-Buriahi, M.S., Mechanical, optical, and gamma-attenuation properties of a newly developed tellurite glass system. Optik, 2022, vol. 266, art. 169355. DOI: 10.1016/j.ijleo.2022.169355
  21. van Pieterson, L., Reid, M.F., Burdick, G.W., Meijerink, A., 4fn→ 4fn-1 5d transitions of the heavy lanthanides: Experiment and theory. Physical review B, 2002, vol. 65, art. 045114. DOI: 10.1103/PhysRevB.65.045114
  22. Rimbacha, A.C., Steudel, F., Ahrens, B., Schweizer, S., Tb3+, Eu3+, and Dy3+ doped lithium borate and lithium aluminoborate glass: Glass properties and photoluminescence quantum efficiency. Journal of Non-Crystalline Solids, 2018, vol. 499, pp. 380–386. DOI: 10.1016/j.jnoncrysol.2018.07.029

Issue

Section

Physics

Pages

93-102

Submitted

2024-06-05

Published

2024-06-28

How to Cite

Hammoud A., Isaev V.A. Optical properties of multicomponent borate glasses doped with trivalent terbium ions. Ecological Bulletin of Research Centers of the Black Sea Economic Cooperation, 2024, vol. 21, no. 2, pp. 93-102. DOI: https://doi.org/10.31429/vestnik-21-2-93-102 (In Russian)