About the prediction of melting temperature of metal nanowires electrochemically deposited into the pores of anodic aluminum oxide

Authors

  • Shilyaeva Yu.I. National Research University of Electronic Technology, Zelenograd, Moscow, Российская Федерация
  • Bardushkin V.V. National Research University of Electronic Technology, Zelenograd, Moscow, Российская Федерация
  • Gavrilov S.A. National Research University of Electronic Technology, Zelenograd, Moscow, Российская Федерация
  • Silibin M.V. National Research University of Electronic Technology, Zelenograd, Moscow, Российская Федерация
  • Yakovlev V.B. National Research University of Electronic Technology, Zelenograd, Moscow, Российская Федерация
  • Borgardt N.I. National Research University of Electronic Technology, Zelenograd, Moscow, Российская Федерация
  • Volkov R.L. National Research University of Electronic Technology, Zelenograd, Moscow, Российская Федерация
  • Smirnov D.I. National Research University of Electronic Technology, Zelenograd, Moscow, Российская Федерация

UDC

538.975:539.319:62 - 405.8

Abstract

The melting point is important thermodynamic characteristic of metallic nanostructures embedded in a matrix. This article focuses on studying of the behavior of metallic threadlike nanocrystals near the melting point. In order to do this, the arrays of indium, tin, and zinc nanocrystals were electrochemically grown in porous anodic alumina matrices with various geometrical parameters and characterized by means of scanning electron microscopy and X-ray diffraction. Melting temperature of nanocrystals was determined experimentally by differential scanning calorimetry. Here we present a solution to the problem of predicting the melting point of the metal nanocrystals enclosed inside the pores of anodic alumina. This solution takes into account the effect of mechanical stresses caused by the differences between the thermal coefficients of linear expansion of the heterogeneity elements during heating. Numerical modeling has been performed for nanocomposites with indium, tin, and zinc nanocrystals. Dependence of melting temperature on the composite structural parameter associated with the concentration of nanocrystals in the bulk of the matrix has been investigated. The results of model calculations were compared with the experimental data.

Keywords:

anodic aluminum oxide, metal nanowires, filamentary composites, differential scanning calorimetry, melting temperature

Acknowledgement

Работа выполнена при поддержке Министерства образования и науки Российской Федерации (122-ГЗ-МФЭ), РФФИ (13-08-00672-а, 14-08-00654-а) и Европейской программы FP7 (PIRSES-GA-2011-295273-NANEL).

Author Infos

Yuliya I. Shilyaeva

ассистент кафедры материалов функциональной электроники Национального исследовательского университета "МИЭТ"

e-mail: shyliaeva@gmail.com

Vladimir V. Bardushkin

д-р физ.-мат. наук, профессор кафедры высшей математики №2 Национального исследовательского университета "МИЭТ"

e-mail: bardushkin@mail.ru

Sergey A. Gavrilov

д-р техн. наук, проректор по научной работе, заведующий кафедрой материалов функциональной электроники Национального исследовательского университета "МИЭТ"

e-mail: pcfme@miee.ru

Maksim V. Silibin

канд. техн. наук, доцент кафедры материалов функциональной электроники Национального исследовательского университета "МИЭТ"

e-mail: sil_m@mail.ru

Viktor B. Yakovlev

д-р физ.-мат. наук, декан вечернего факультета Национального исследовательского университета "МИЭТ"

e-mail: yakovlev@miee.ru

Nikolay I. Borgardt

д-р физ.-мат. наук, заведующий кафедрой общей физики Национального исследовательского университета "МИЭТ"

e-mail: gpd@miee.ru

Roman L. Volkov

канд. физ.-мат. наук, старший научный сотрудник центра коллективного пользования "Диагностика и модификация микроструктур и нанообъектов" Национального исследовательского университета "МИЭТ"

e-mail: lemi@miee.ru

Dmitriy I. Smirnov

инженер научно-исследовательской лаборатории радиационных методов, технологий и анализа Национального исследовательского университета "МИЭТ"

e-mail: rmta@miee.ru

References

  1. Jaya Sarkar, Gobinda Gopal Khan, Basumallick A. Nanowires: properties, applications and synthesis via porous anodic aluminium oxide template. Bulletin Mater. Sci., 2007, vol. 30, no. 3, pp. 271-290.
  2. Gavrilov S., Nosova L., Sieber I., Belaidi A., Dloczik L., Dittrich Th. Synthesis of semiconductor nanowires by pulsed current electrodeposition of metal with subsequent sulfurization. Phys. Status Solidi A, 2005, vol. 202, no. 8, pp. 1497-1501.
  3. Xu S.H., Fei G.T., Zhang Y., Li X.F., Jin Z., Zhang L.D. Size-dependent melting behavior of indium nanowires. Phys. Lett. A, 2011, vol. 375, pp. 1746-1750.
  4. Wang X.W., Fei G.T., Zheng K., Jin Z., Zhang L.D. Size-dependent melting behaviour of Zn nanowires arrays. Appl. Phys. Lett., 2011, vol. 88, pp. 173114-173116.
  5. Bardushkin V.V., Shilyaeva Yu.I., Yakovlev V.B. Koncentracija naprjazhenij i deformacij v poristozapolnennom metallicheskimi nitevidnymi nanokristallami anodnom okside aljuminija [Concentration of stresses and strains in porous anodic alumina filled with metallic nanowires]. \textit{Deformacija i razrushenie materialov} [Deformation and destruction of materials], 2013, no. 10, pp. 24-29. (In Russian)
  6. Shilyaeva Yu.I., Bardushkin V.V., Silibin M.V., Gavrilov S.A., Yakovlev V.B., Pyatilova O.V. Vliyanie struktury i termouprugikh svoystv komponentov na srednie napryazheniya v anodnom okside alyuminiya s porami, zapolnennymi metallicheskimi nitevidnymi nanokristallami [Effect of the structure and thermoelastic properties of components on the average stress in anodic aluminum oxide having pores filled with metallic nanowires]. Neorganicheskie materialy [Inorganic materials], 2013, vol. 49, pp. 676-680. (In Russian)
  7. Shilyaeva Yu.I., Bardushkin V.V., Silibin M.V., Gavrilov S.A., Yakovlev V.B., Pyatilova O.V. Ob"emnaya plotnost' energii deformatsii v poristozapolnennom metallicheskimi nitevidnymi nanokristallami anodnom okside alyuminiya [Bulk density of the energy of deformation in an anodic aluminum oxide with pores filled by threadlike metal nanocrystals]. Russ. J. Phys. Chem. A, 2013, vol. 87, pp. 1870-1874. (In Russian)
  8. Bardushkin V.V., Shilyaeva Yu.I., Yakovlev V.B. Effektivnye uprugiye kharakteristiki poristozapolnennogo metallicheskimi nitevidnymi nanokristallami anodnogo oksida aljuminija [Effective elastic characteristics of the highly ordered metal-filled anodic alumina]. Ecological Bulletin of Research Centers of the Black Sea Economic Cooperation, 2013, no. 2, pp. 21-26. (In Russian)
  9. Masuda H., Fukuda K. Ordered metal nanohole arrays made by a two-step replication of honeycomb structures of anodic alumina. Science, 1995, vol. 268, pp. 1466-1468.
  10. Gamburg Yu.D. Galvanicheskie pokrytiya. Spravochnik po primeneniyu [Electroplated coatings. Handbook of the applications]. Moscow, Tehnosfera Publ., 2006, 216 p. (In Russian)
  11. Lu K., Li Y. Homogeneous nucleation catastrophe as a kinetic stability limit for superheated crystal. Phys. Rev. Lett., 1998, vol. 80, pp. 4474-4477.
  12. Guisbiers G., Pereira S. Theoretical investigation of size and shape effects on the melting temperature of ZnO nanostructures. Nanotechnology, 2007, vol. 18, pp. 435710-435716.
  13. Kinloch A.J. Adhesion and Adhesives: Science and Technology. London, Chapman and Hall, 1987, 441 p.
  14. Grigor'ev I.S., Meilikhov E.Z. (Eds.) Fizicheskie velichiny: Spravochnik [Physical Quantities: A Handbook]. Moscow, Energoatomizdat, 1991, 1232 p. (In Russian)
  15. Korol'kov A.M. Litejnye svojstva metallov i splavov [Casting properties of metals and alloys]. Moscow, Izd. Akad. Nauk Publ., 1960, 196 p. (In Russian)
  16. Xia Z., Riester L., Sheldon B.W., Curtin A., Liang J., Yin A., Xu J.M. Mechanic properties of highly ordered nanoporous anodic alumina membranes. Rev. of Adv. Mater. Sci., 2004, vol. 34, pp. 131-139.
  17. Gu P., Miao H., Liu Z.T., Wu X.P., Zhao J.H. Investigation of elastic modulus of nanoporous alumina membrane. J. Mater. Sci., 2004, vol. 39, pp. 3369-3373.
  18. Fernandez-Romero L., Montero-Moreno J.M., Pellicer E., Peiro F., Cornet A., Morante J.R., Sarret M., Muller C. Assessment of the thermal stability of anodic alumina membranes at high temperatures. Mater. Chem. Phys., 2008, vol. 111, pp. 542-547.
  19. Shermergor T.D. Teoriya uprugosti mikroneodnorodnykh sred [Theory of elasticity of microinhomogeneous media]. Moscow, Nauka Publ., 1977, 399 p. (In Russian)
  20. Bardushkin V., Yakovlev V. Mechanics of Microstructures (Effective and Local Properties of Textured Polycrystals and Composites). Germany, Saarbr\"{u}ken, LAP (Lambert Academic Publishing), 2011, 164 p.

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Issue

2014. No. 3

Pages

84-94

Submitted

2014-05-30

Published

2014-09-29

How to Cite

Shilyaeva Yu.I., Bardushkin V.V., Gavrilov S.A., Silibin M.V., Yakovlev V.B., Borgardt N.I., Volkov R.L., Smirnov D.I. About the prediction of melting temperature of metal nanowires electrochemically deposited into the pores of anodic aluminum oxide. Ecological Bulletin of Research Centers of the Black Sea Economic Cooperation, 2014, no. 3, pp. 84-94. (In Russian)

Copyright (c) 2014 Shilyaeva Yu.I., Bardushkin V.V., Gavrilov S.A., Silibin M.V., Yakovlev V.B., Borgardt N.I., Volkov R.L., Smirnov D.I.

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