Analysis of cyanidin, delphinidin, malvidin and pelargonidin anthocyanins in food products by infrared spectroscopy
UDC
543.421/.424DOI:
https://doi.org/10.31429/vestnik-20-4-71-78Abstract
In the present work investigated peculiarities of chemical structure of most common in nature anthocyanins, namely, cyanidin, delphinidin, malvidin, and pelargonidin. Represented structural and dynamic models of these molecules, as well as their corresponding theoretical IR-spectrum calculated within the framework of the quantum model DFT/RB3LYP/6-31G(d,p). Marked the characteristic peaks for each of these anthocyanins, allowing one anthocyanin to be distinguished from another in the composition of the substance: for cyanidin – 1223 cm-1, delphinidin – 1176~cm-1, malvidin – 1480 cm-1, and pelargonidin – 1197~cm-1. Theoretical calculations confirmed by an experiment consisting in investigation of practically obtained IR-spectrum of pomegranate fruits (Punica granatum), strawberry (Fragaria viridis), blueberry (Vaccinium uliginosum), red onion (Allium cepa) and red cabbage (Brassica oleracea). Obtained results have wide possibilities for approbation and implementation in the food and pharmaceutical industries.
Keywords:
anthocyanins, IR-spectrum, cyanidin, delphinidin, malvidin, pelargonidinAcknowledgement
References
- Węglińska, M., Szostak, R., Kita, A., Nemś, A., Mazurek, S., Determination of nutritional parameters of bee pollen by Raman and infrared spectroscopy. Talanta, 2020, vol. 212, p. 120790. DOI: 10.1016/j.talanta.2020.120790
- Liu, N., Cheng, S., Wang, X., Li, Z., Zheng, L., Lyu, Ya., Ao, X., Wu, H., Characterization of microplastics in the septic tank via laser direct infrared spectroscopy. Water Research, 2022, vol. 226, p. 119293. DOI: 10.1016/j.watres.2022.119293
- Zhuang, J., Li, M., Pu, Y., Ragauskas, A.J., Yoo, C.G., Observation of Potential Contaminants in Processed Biomass Using Fourier Transform Infrared Spectroscopy. Appl. Sci., 2020, vol. 10, no. 12, p. 4345. DOI: 10.3390/app10124345
- Веснин, В.Л., Мурадов, В.Г., Применение инфракрасной спектроскопии для анализа углеводородных смесей. Известия Самарского научного центра Российской академии наук, 2014, т. 16, № 4, с. 63–68. [Vesnin, V.L., Muradov, V.G., Application of infrared spectroscopy for the analysis of hydrocarbon mixtures. Izvestiya samarskogo nauchnogo tsentra Rossiyskoy akademii nauk = Proceedings of the Samara Scientific Center of the Russian Academy of Sciences, 2014, vol. 16, no. 4, p. 63–68. (in Russian)]
- Неханов, Д.В., Котов, В.В., Стекольников, К.Е., Селеменев, В.Ф., Карпов, С.И., Лукин, А.Н., Определение состава препаратов гуминовых кислот различной чистоты методами спектроскопии. Сорбционные и хроматографические процессы, 2009, т. 9, № 5, с. 665–670. [Nekhanov, D.V. Kotov, V.V., Stekolnikov, K.E., Selemenev, V.F., Karpov, S.I., Lukin, A.N., Determination of the composition of humic acid preparations of various purity by spectroscopy methods. Sorbtsionnyye i khromatograficheskiye protsessy = Sorption and Chromatography Processes, 2009, vol. 9, no. 5, p. 665–670. (in Russian)]
- Barth, A., Infrared spectroscopy of proteins. Biochimica et Biophysica Acta (BBA) – Bioenergetics, 2007, vol. 1767, no. 9, p. 1073–1101. DOI: 10.1016/j.bbabio.2007.06.004
- Halbwirth, H., The Creation and Physiological Relevance of Divergent Hydroxylation Patterns in the Flavonoid Pathway. International journal of molecular sciences, 2010, vol. 11, no. 2, p. 595–621. DOI: 10.3390/ijms11020595
- Alappat, B., Alappat, J., Anthocyanin Pigments: Beyond Aesthetics. Molecules, 2020, vol. 25, no. 23, p. 5500. DOI: 10.3390/molecules25235500
- Московская глазная клиника (дата обращения 27.05.2023) [Moscow eye clinic (accessed 27.05.2023)]. URL: https://mgkl.ru/patient/aptechka/antozian-forte
- Tena, N., Martín, J., Asuero, A.G., State of the Art of Anthocyanins: Antioxidant Activity, Sources, Bioavailability, and Therapeutic Effect in Human Health. Antioxidants, 2020, vol. 9, no. 5, p. 451. DOI: 10.3390/antiox9050451
- Frisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseria, G.E., Robb, M.A., Cheeseman, J.R., Scalmani, G., Barone, V., Mennucci, B., Petersson, G.A., Nakatsuji, H., Caricato, M., Li, X., Hratchian, H.P., Izmaylov, A.F., Bloino, J., Zheng, G., Sonnenberg, J.L., Hada, M., Ehara, M., Toyota, K., Fukuda, R., Hasegawa, J., Ishida, M., Nakajima, T., Honda, Y., Kitao, O., Nakai, H., Vreven, T., Montgomery, Jr., J.A., Peralta, J.E., Ogliaro, F., Bearpark, M., Heyd, J.J., Brothers, E., Kudin, K.N., Staroverov, V.N., Kobayashi, R., Normand, J., Raghavachari, K., Rendell, A., Burant, J.C., Iyengar, S.S., Tomasi, J., Cossi, M., Rega, N., Millam, J.M., Klene, M., Knox, J.E., Cross, J.B., Bakken, V., Adamo, C., Jaramillo, J., Gomperts, R., Stratmann, R.E., Yazyev, O., Austin, A.J., Cammi, R., Pomelli, C., Ochterski, J.W., Martin, R.L., Morokuma, K., Zakrzewski, V.G., Voth, G.A., Salvador, P., Dannenberg, J.J., Dapprich, S., Daniels, A.D., Farkas, O., Foresman, J.B., Ortiz, J.V., Cioslowski, J., Fox, D.J., Gaussian 09, Revision A.02. Gaussian, Inc., Wallingford CT, 2009.
Downloads
Submitted
Published
How to Cite
Copyright (c) 2024 Stepanovich E.Yu., Aliyev P.N.
This work is licensed under a Creative Commons Attribution 4.0 International License.