The 15N NMR investigation in 1-n-butyl-3-methyl-imidazolium chloride

Authors

  • Kashaev D.V. Kuban State University, Krasnodar, Russian Federation
  • Bolotin S.N. Kuban State University, Krasnodar, Russian Federation
  • Buzko V.Yu. Joint Owners Private Corporation Regional Interdisciplinary Center "Yugtehinform", Krasnodar, Russian Federation
  • Sukhno I.V. Joint Owners Private Corporation Regional Interdisciplinary Center "Yugtehinform", Krasnodar, Russia, Russian Federation

UDC

543.429.23: 544.018.4: 544.275.3

EDN

OZCFYT

Abstract

Nuclear Magnetic-Resonance spectroscopy can provide useful information about intramolecular structure in organic ionic liquids (IL) and is the powerful structural tool in physics and chemistry of liquid state. In this report we performed the first results on INEPT derived 15N NMR study of 1-Butyl-3-Methyl-Imidazolium Chloride ([BMIm][Cl]) ionic liquid in the wide temperature range 298-408 K.

Keywords:

nuclear magnetic resonance, NMR spectroscopy, INEPT, 15N, ionic liquid, 1-Butyl-3-ethyl-Imidazolium Chloride, relaxation

Authors info

  • Denis V. Kashaev

    инженер Научно образовательного центра "Диагностика структуры и свойств наноматериалов" центра коллективного пользования Кубанского государственного университета

  • Sergey N. Bolotin

    канд. хим. наук, доцент кафедры геоэкологии и природопользования Кубанского государственного университета

  • Vladimir Yu. Buzko

    канд. хим. наук, старший научный сотрудник лаборатории молекулярного моделирования химических процессов и соединений РМЦ "Югтехинформ"

  • Igor V. Sukhno

    канд. хим. наук, заведующий лабораторией молекулярного моделирования химических процессов и соединений РМЦ "Югтехинформ"

References

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  5. Remsing R.C., Wildin J.L., Rapp A.L., Moyna G. Hydrogen Bonds in Ionic Liquids Revisited: 35/37Cl NMR Studies of Deuterium Isotope Effects in 1-n-Butyl-3-Methylimidazolium Chloride // J. Phys. Chem. B, 2007. Vol. 111. No 40. P. 11619-11621.
  6. Кашаев Д.В., Бузько В.Ю., Сухно И.В. Изучение динамики в 1-н-бутил-3-метилимидазолия хлориде методом 35Cl ЯМР // Известия Вузов. Химия и химическая технология. 2011. Т. 54. №12. С. 111-113.

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Issue

Vol.  (2012) No. 2

Pages

89-91

Section

Briefs

Dates

Submitted

April 17, 2011

Accepted

May 23, 2011

Published

June 29, 2012

How to Cite

[1]
Kashaev, D.V., Bolotin, S.N., Buzko, V.Y., Sukhno, I.V., The 15N NMR investigation in 1-n-butyl-3-methyl-imidazolium chloride. Ecological Bulletin of Research Centers of the Black Sea Economic Cooperation, 2012, № 2, pp. 89–91.

License

Copyright (c) 2012 Кашаев Д.В., Болотин С.Н., Бузько В.Ю., Сухно И.В.

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

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