Influence of structural features of fullerene-containing material deposited from solution on its resistive properties
UDC
53.06, 538.9, 621.31, 621.38DOI:
https://doi.org/10.31429/vestnik-15-4-85-92Abstract
The article deals with carbon films obtained by precipitation from suspensions of fullerene-containing materials (FСM) in benzene at different concentrations of C60 fullerene. Fullerene-containing material was obtained by low-temperature cracking in the processing of polymeric organic raw materials. Fullerene C60 to be added to FCM in the amount of 1–70% was produced by the method of electric arc spraying of graphite and separation using toluene. For the deposition of films, glass substrates and glass substrates with a layer of conducting indium tin oxide were used. After obtaining the film structures, the study of their surface was carried out using optical microscopy. The study showed that at low concentrations of C60 (less than 30%), individual microparticles with a size of several microns form on the surface of the films, while at high concentrations their size reaches 10 microns and more. In addition, at high concentrations, microparticles are arranged in chains. Investigation of the temperature dependences of the resistance of film structures showed that at fullerene concentrations up to 10%, the conductivity is combined. For large C60 percentages, characteristics typical of semiconductors were observed. At low fullerene concentrations in FСM (1‒5%), the current-voltage characteristics of the film structures were linear. With its increase, a nonlinear dependence of the current on voltage was observed.
Keywords:
carbon composites, fullerene-containing material, fullerene, deposition from solution, temperature dependence of resistance, current-voltage characteristics, concentrationReferences
- Елистратова М.А., Захарова И.Б., Романов Н.М., Паневин В.Ю., Квятковский О.Е. Спектральная зависимость фотолюминесценции тонких пленок молекулярных комплексов ZnTPP–C60 и CuTPP–C60 // Физика и техника полупроводников. 2016. Т. 50. Вып. 9. С. 1213–1219. [Elistratova, M.A., Zakharova, I.B., Romanov, N.M., Panevin, V.Yu., Kvyatkovskii, O.E. Spektral'naya zavisimost' fotolyuminestsentsii tonkih plenok molekulyarnyh kompleksov ZnTPP–C60 i CuTPP–C60 [Photoluminescence spectroscopy of thin films of CuTPP–C60 and ZnTPP–C60 molecular complexes]. Fizika i tekhnika poluprovodnikov [Physics and technology of semiconductors], 2016, vol. 50. iss. 9, pp. 1213–1219. (In Russian)]
- Захарова И.Б., Квятковский О.Е., Доненко Е.Г., Бирюлин Ю.Ф. Оптические свойства, электронная структура и колебательный спектр тонких пленок С60-ТРР // Физика твердого тела. 2009. Т. 51. Вып. 9. С. 1860–1867. [Zakharova, I.B., Kvyatkovskiy, O.E., Donenko, E.G., Biryulin, Yu.F. Opticheskie svojstva, elektronnaya struktura i kolebatel'nyy spektr tonkih plenok C60-TPP [Optical properties, electronic structure and vibrational spectrum of C60-TPP thin films]. Fizika tvyordogo tela [Solid state physics], 2009, vol. 51, iss. 9, pp. 1860–1867. (In Russian)]
- Мелетов К.П. Фазовые переходы при высоком давлении в молекулярном донорно-акцепторном комплексе фуллерена {Hg(dedtc)2}2·C60 // Физика твердого тела. 2014. Т. 56. Вып. 8. С. 1636–1641. [Meletov, K.P. Fazovye perekhody pri vysokom davlenii v molekulyarnom donorno-aktseptornom komplekse fullerena {Hg(dedtc)2}2·C60 [Phase transitions at high pressure in the molecular donor-acceptor complex of {Hg(dedtc)2}2·C60 fullerene]. Fizika tvyordogo tela [Solid state physics], 2014, vol. 56, iss. 8, pp. 1636–1641. (In Russian)]
- Мазинов А.С., Работягов К.В., Гурченко В.С., Тютюник А.С. Влияние структурных особенностей фуллеренсодержащего материала на его резистивные свойства // Экологический вестник научных центров Черноморского экономического сотрудничества. 2018. Т. 15. Вып. 2. С. 86–93. [Mazinov, A.S., Rabotyagov, K.V., Gurchenko, V.S., Tyutyunik, A.S. Vliyanie strukturnyh osobennostej fullerensoderzhashchego materiala na yego rezistivnye svojstva [Influence of structural features of fullerene-containing material on its resistive properties]. Ekologicheskij vestnik nauchnyh tsentrov Chernomirskogo ekonomicheskogo sotrudnichestva [Ecological Bulletin of the Black Sea Economical Society], 2018, vol. 15, iss. 2, pp. 86–93. (In Russian)]
- Шевченко А.И., Работягов К.В., Максимова Е.М., Наухацкий И.А., Батиашвили Л.А. Фуллеренсодержащий материал, полученный низкотемпературным крекингом из резиносодержащих отходов // Вестник Тамбовского университета. Серия Естественные и технические науки. 2017. Т. 22. Вып. 2. С. 459–463. DOI: 10.20310/1810-0198-2017-22-2-459-463 [Shevchenko, A.I., Rabotyagov, K.V., Maksimova, E.M., Naukhatskiy, I.A., Batiashvili, L.A. Fullerensoderzhashchij material, poluchennyj nizkotemperaturnym krekingom iz rezinosoderzhashchih othodov [Fullerene-containing material received by low-temperature cracking from rubber-containing wastes]. Vestnik Tambovskogo universiteta. Seriya Estestvennye i tekhnicheskie nauki [Tambov University Reports. Series: Natural and Technical Sciences], 2017, vol. 22, iss. 2, pp. 459–463. DOI: 10.20310/1810-0198-2017-22-2-459-463 (In Russian)]
- Работягов К.В., Сай Е.В., Максимова Е.М., Наухацкий И.А., Карпенко Н.И., Шевченко А.И., Мазинов А.С. Исследование структуры и физико-химических свойств пористых углеродных материалов, полученных низкотемпературным крекингом // Ученые записки Крымского федерального университета имени В.И. Вернадского. Биология. Химия. 2015. Т. 1 (67). № 3. С. 125–131. [Rabotyagov, K.V., Say, E.V., Maksimova, E.M., Nauhacky, I.A., Karpenko, N.I., Shevchenko, A.I., Mazinov, A.S. Issledovanie struktury i fiziko-himicheskih svojstv poristyh uglerodnyh materialov, poluchennyh nizkotemperaturnym krekingom [Investigation of the structure and physicochemical properties for porous carbon materials obtained by low-temperature cracking]. Uchyonye zapiski Krymskogo federal'nogo universiteta imeni V.I. Vernadskogo. Biologiya. Himiya [Scientific Notes of V.I. Vernadsky Crimean Federal University. Biology. Chemistry], 2015, vol. 1 (67), iss. 3, pp. 125–131. (In Russian)]
- Laiho A., Ras R.H.A., Valkama S., Ruokolainen J. Control of self-assembly by charge-transfer complexation between C60 fullerene and electron donating units of block copolymers // Macromolecules. 2006. Vol. 39. P. 7648–7653.
- Берёзкин В.И., Попов В.В. Перколяционный переход в углеродном композите на основе фуллеренов и терморасширенного графита // Физика твердого тела. 2018. Т. 60. Вып. 1. С. 202–206. [Berezkin, V.I., Popov, V.V. Perkolyatsionnyj perekhod v uglerodnom kompozite na osnove fullerenov i termorasshirennogo grafita [Percolation transition in carbon composite based on fullerenes and thermally expanded graphite]. Fizika tvyordogo tela [Solid state physics], 2018, vol. 1, iss. 60, pp. 202–206. (In Russian)]
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Copyright (c) 2018 Мазинов А.С., Гурченко В.С., Тютюник А.С., Шевченко А.И.
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