X-ray fluorescence detection of aluminum and uranium in water

Authors

  • Lashtaberga O.O. Kuban State University, Krasnodar, Russian Federation
  • Temerdashev Z.A. Kuban State University, Krasnodar, Russian Federation
  • Sorokina N.M. Moscow State University, Moscow, Russian Federation
  • Tsyzin G.I. Moscow State University, Moscow, Russian Federation

UDC

543.427.2 : 543.054

EDN

JUVMFR

Abstract

Conditions for aluminum and uranium preconcentration out of solutions on thin-layer cellulose filters were found. Uranium was recovered on the filters with grafted aminocarboxylic groups (DETATA), aluminum on the hydrophobised cellulose filters as the complexes with 8-hydroxiquinoline. The X-ray fluorescence methods were offered aimed to detect these elements in water. Detection limits were achieved at 0.004 ppm for uranium and at 0.03 ppm for aluminum. Accuracy of the method was proved by the analysis of spiked river, sea, mineral and tap water.

Keywords:

X-ray fluorescent method, sorption concentrating method

Authors info

  • Olga O. Lashtaberga

    научный сотрудник кафедры аналитической химии Кубанского государственного университета

  • Zaual A. Temerdashev

    д-р хим. наук, профессор, заведующий кафедрой аналитической химии Кубанского государственного университета

  • Nadezhda M. Sorokina

    канд. хим. наук, доцент кафедры аналитической химии Московского государственного университета им. М.В. Ломоносова

  • Grigoriy I. Tsyzin

    д-р хим. наук, профессор, ведущий научный сотрудник кафедры аналитической химии Московского государственного университета им. М.В. Ломоносова

References

  1. Ping L., Matsumoto K., Fuwa K. Internal standardization in energy-dispersive x-ray fluorescence spectrometric determination of trace elements in urine after preconcentration with a chelating filter // Anal. Chem. 1983. Vol. 55. P. 1819-1821.
  2. Цизин Г.И., Серегина И.Ф., Сорокина Н.М., Формановский А.А., Золотов Ю.А. Рентгенофлуоресцентное определение токсичных элементов в водах с использованием сорбционных фильтров // Заводская лаборатория. 1993. Т. 59. №10. С. 1-5.
  3. Varshal G.M., Velyukhanova T.K., Pavlutskaya V.I, Starshinova N.P., Formanovsky A.A., Tsysin G.I., Zolotov Yu.A. DETATA-filters for metal preconcentration and multielement determination in natural waters // Intern. J. Environ. Anal. Chem. 1994. Vol. 57. P. 107-124.
  4. Smits J., Nelissen J., Van Grieken R. Comparison of preconcentration procedures for trace metals in natural waters // Anal. Chim. Acta. 1979. Vol. 111. P. 215-226.
  5. Gennaro M.C., Sarzanini C., Mentasti E., Baiocchi C. Use of methyliminodiacetic acid bound to cellulose for preconcentration and determination of trace-metal cations // Talanta. 1985. Vol. 32. No 10. P. 961-966.
  6. Gennaro M.C., Mentasti E., Sarzanini C. EDTA bound on cellulose for the preconcentration of metal traces. // New J. of Chem. 1986. Vol. 10. No 2. P. 107-110.
  7. Häubl G., Wegscheider W., Knapp G. Preparation of cellulose filters with covalently bound dithiocarbamate, 8-hydroxyquinoline and aminocarboxylic acid functional groups // Angew. Makromol. Chem. 1984. Vol. 121. P. 209-222.
  8. Цизин Г.И., Формановский А.А., Михура И.В., Евтикова Г.А., Соколов Д.П., Маров И.Н. Комплексы меди (II) с конформационно подвижными аминокарбоксильными полимерными лигандами // Журн. неорг. химии. 1990. Т. 35. №4. C. 960-966.
  9. Burba P., Rocha J., Klockow D. Labile complexes of trace metals in aquatic humic substances: investigations by means of an ion exchange-based flow procedure // Fresenius J. Anal. Chem. 1994. Vol. 349. P. 800-807.
  10. Мясоедова Г.В., Саввин С.Б. Хелатообразующие сорбенты. М.: Наука. 1984. 171 с.
  11. Tsysin G.I., Mikhura I.V., Formanovsky A.A., Zolotov Yu.A. Сellulose fibrous sorbents with conformationally flexible aminocarboxylic groups for preconcentration of metals // Mikrochim. Acta. 1991. III. P. 53-60.

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Issue

Pages

82-85

Section

Physics

Dates

Submitted

January 13, 2008

Accepted

February 17, 2008

Published

March 28, 2008

How to Cite

[1]
Lashtaberga, O.O., Temerdashev, Z.A., Sorokina, N.M., Tsyzin, G.I., X-ray fluorescence detection of aluminum and uranium in water. Ecological Bulletin of Research Centers of the Black Sea Economic Cooperation, 2008, № 1, pp. 82–85.

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