Spectral and conductive characteristics of fullerene-based thin-film structures

Authors

  • Mazinov A.A. Vernadsky Crimean Federal University, Simferopol, Russian Federation
  • Gurchenko V.S. Vernadsky Crimean Federal University, Simferopol, Russian Federation
  • Shevchenko A.I. Vernadsky Crimean Federal University, Simferopol, Russian Federation
  • Arutinov N.E. Vernadsky Crimean Federal University, Simferopol, Russian Federation
  • Tutunik A.S. Vernadsky Crimean Federal University, Simferopol, Russian Federation

UDC

53.06, 538.9, 621.31, 621.38

EDN

LCAGOF

DOI:

10.31429/vestnik-16-2-48-58

Abstract

In the present paper we consider carbon films obtained by the method of sequential deposition from fullerene solutions in various types of solvents. Micrographs are presented to estimate the surface geometry of thin-film structures. So, using various solvents, it is possible to form various geometrical objects depending on the functional purpose of the films. At the same time, nanostructured objects can have the form of both bulk polygons (in our case, hexagons) and star-shaped branching structures. The IR spectra of the obtained samples were analyzed and their comparative characteristics were given for a volume of a precipitated solution of 0.15 ml and 1 ml. Depending on the type of initial solvent, both solvent peaks, fullerene, and complex organic impurities can be present in the fabricated samples. From the presence of solvent peaks, it is possible to make an assumption about the crystallization of solvates and their preservation in the film after drying. The conductive properties of thin-film structures are investigated. The use of five types of solvents made it possible to change linear resistances from hundreds to thousands of GOhms with a volume of 0.15 ml applied. An increase in the volume of the nanocrystalline fraction (1 ml of solution) made it possible to reduce the resistance to tens of GOhms

It is worth noting that the mechanisms of the action of the active solvent environment on the morphology of the synthesized objects are not entirely clear, however, studies conducted to obtain nanostructures from fullerene solutions will be effective and, in our opinion, for controlled self-assembly of other functional organic systems.

Keywords:

fullerene, C60, solvent, current-voltage characteristic, thin-film structures, topology

Authors info

  • Alim A. Mazinov

    канд. техн. наук, доцент кафедры радиофизики и электроники Физико-технического института Крымского федерального университета им. В.И. Вернадского

  • Vladimir S. Gurchenko

    студент магистратуры Физико-технического института Крымского федерального университета им. В.И. Вернадского

  • Alexey I. Shevchenko

    канд. физ.-мат. наук, ассистент кафедры радиофизики и электроники Физико-технического института Крымского федерального университета им. В.И. Вернадского

  • Nikita E. Arutinov

    студент бакалавриата Физико-технического института Крымского федерального университета им. В.И. Вернадского

  • Andrey S. Tutunik

    аспирант кафедры радиофизики и электроники Физико-технического института Крымского федерального университета им. В.И. Вернадского

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Issue

Vol. 16 (2019) No. 2

Pages

48-58

Section

Physics

Dates

Submitted

March 23, 2019

Accepted

April 19, 2019

Published

June 28, 2019

How to Cite

[1]
Mazinov, A.A., Gurchenko, V.S., Shevchenko, A.I., Arutinov, N.E., Tutunik, A.S., Spectral and conductive characteristics of fullerene-based thin-film structures. Ecological Bulletin of Research Centers of the Black Sea Economic Cooperation, 2019, т. 16, № 2, pp. 48–58. DOI: 10.31429/vestnik-16-2-48-58

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Copyright (c) 2019 Мазинов А.С., Гурченко В.С., Шевченко А.И., Арутинов Н.Э., Тютюник А.С.

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